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11–12Chemistry 11–12 Syllabus (2025)

Record of changes
Implementation from 2028
Expand for detailed implementation advice

Content

Year 12

Equilibrium

Relevant Working scientifically outcomes and content must be integrated with each focus area. All the Working scientifically outcomes and content must be addressed by the end of Year 12.

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Dynamic equilibrium
  • Account for the characteristics of a dynamic equilibrium system using collision theory

  • Explain why macroscopic properties remain constant at equilibrium

  • Conduct a laboratory experiment to demonstrate the reversibility of a chemical reaction

  • Conduct a practical investigation to model a dynamic equilibrium system

  • Discuss the impact of a closed system on dynamic equilibrium

Factors that affect equilibrium
  • Use Le Chatelier’s principle to predict the effects of temperature, concentration, volume and pressure changes on equilibrium systems

  • Conduct a practical investigation to analyse the effects of temperature and concentration changes on a system at equilibrium

  • Use collision theory to explain the effects of concentration and temperature changes on equilibrium systems using qualitative data

  • Use collision theory to explain the effect of pressure changes on gaseous equilibrium systems using qualitative data

  • Conduct a practical investigation to analyse pressure and volume changes in a gaseous system at equilibrium

  • Use Le Chatelier’s principle and collision theory to address real-world applications involving equilibrium systems

  • Justify methods associated with temperature, concentration and pressure that are used to increase yield in chemical equilibria

  • Conduct a secondary-source investigation to analyse the manipulation of reaction conditions to ensure economical production of an industrial chemical

Calculating the equilibrium constant
  • Determine equilibrium expressions in terms of the equilibrium constant (Keq) for reactions occurring in homogeneous solution equilibrium systems and homogeneous gas equilibrium systems
  • Perform calculations to find the value of Keq and concentrations of substances within an equilibrium system, and use these values to predict the direction of a reaction
  • Calculate the reaction quotient (Q) using concentrations of substances in chemical systems, and use these values to determine if a system is at equilibrium
  • Analyse the effect of temperature on the value of Keq using qualitative data
  • Conduct a practical investigation to determine Keq of the iron(III) thiocyanate equilibrium system
  • Solve equilibrium system problems using Keq, 1Keq and Q
Solution equilibria
  • Use diagrams to model the processes by which bonds break and form during the dissolution of ionic compounds in water

  • Conduct a laboratory experiment to construct a set of solubility rules for the cations barium (Ba2+), calcium (Ca2+), silver (Ag+), copper(II) (Cu2+), iron(II) (Fe2+) and iron(III) (Fe3+)
  • Conduct a laboratory experiment to construct a set of solubility rules for the anions chloride (Cl-), bromide (Br-), iodide (I-), hydroxide (OH-), acetate (CH3COO-), carbonate ( CO 3 2 ), sulfate ( SO 4 2 ) and phosphate ( PO 4 3 )
  • Use secondary sources to assess the accuracy of the solubility rules derived in the solubility experiments

  • Conduct a scientific investigation applying known solubility rules and identify 2 unknown ions in the resulting solution

  • Derive equilibrium expressions for saturated solutions in terms of Ksp
  • Use the Ksp value of ionic substances to determine their solubility in g L-1 and mol L-1
  • Predict the formation of a precipitate given the standard reference values for Ksp
  • Solve problems using Ksp solubility and equilibrium concentration data in equilibrium systems
  • Conduct a secondary-source investigation to analyse the use of solubility equilibria to monitor the presence of lead (Pb2+) and phosphate ( PO 4 3 ) ions in the environment
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